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We study asymptotic behavior of the stability thresholds of a big line bundle, and prove explicit bounds on the error terms. This answers Jin--Rubinstein--Tian's questions affirmatively. A key step in our proof is to show that the stability thresholds of a big line bundle can always be computed by quasi-monomial valuations. This generalizes Blum--Jonsson's result on the stability thresholds of an ample line bundle.